翻訳と辞書 Words near each other ・ Markovec ・ Markovi Kuli ・ Markovia ・ Markovian ・ Markovian arrival process ・ Markovian discrimination ・ Markovic affair ・ Markovica ・ Markovics ・ Marković ・ Marković Polje ・ Markoviće ・ Markovićevo ・ Markovići (Goražde) ・ Markovići (Kiseljak) ・ Markovnikov's rule ・ Markovo ・ Markovo Airport ・ Markovo Kale ・ Markovo Polje ・ Markovo Republic ・ Markovo tepe ・ Markovo, Chukotka Autonomous Okrug ・ Markovo, Kamnik ・ Markovo, Russia ・ Markovski ・ Markovsky ・ Markovščina ・ Markov–Kakutani fixed-point theorem ・ Markov–Krein theorem Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Markovnikov's rule ： ウィキペディア英語版 Markovnikov's rule In organic chemistry, Markovnikov's rule or Markownikoff's rule describes the outcome of some addition reactions. The rule was formulated by Russian chemist Vladimir Vasilevich Markovnikov in 1870. == Explanation == The rule states that with the addition of a protic acid HX to an unsymmetrical alkene, the acid hydrogen (H) becomes attached to the carbon with fewer alkyl substituents, and the halide (X) group becomes attached to the carbon with more alkyl substituents. Alternatively, the rule can be stated that the hydrogen atom is added to the carbon with the greater number of hydrogen atoms while the X component is added to the carbon with the fewer number of hydrogen atoms.〔Organic Chemistry, 6th Edition, by John McMurry. Section 6.9, page 187〕 The same is true when an alkene reacts with water in an addition reaction to form an alcohol which involve formation of carbocations. The hydroxyl group (OH) bonds to the carbon that has the greater number of carbon–carbon bonds, while the hydrogen bonds to the carbon on the other end of the double bond, that has more carbon–hydrogen bonds. The chemical basis for Markovnikov's Rule is the formation of the most stable carbocation during the addition process. The addition of the hydrogen ion to one carbon atom in the alkene creates a positive charge on the other carbon, forming a carbocation intermediate. The more substituted the carbocation (the more bonds it has to carbon or to electron-donating substituents) the more stable it is, due to induction and hyperconjugation. The major product of the addition reaction will be the one formed from the more stable intermediate. Therefore, the major product of the addition of HX (where X is some atom more electronegative than H) to an alkene has the hydrogen atom in the less substituted position and X in the more substituted position. However, the other less substituted, less stable carbocation will still be formed to some degree, and will proceed to form the minor product with the opposite attachment of X. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Markovnikov's rule」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.